2847KbAbstractAs a precursor to the ESR and relaxation studies steroids steroids steroids, measurements of the dielectric constants and loss for pure single crystals of calcium tungstate have been made at 1 MHz and room temperature giving values of e (_a) 11.3 0.4, e (_c) = 9.1 + 0.4 and 5 x 10 (^ 3) which agree closely with Grower and Fang’s. Our measurements were extended to frequencies up to 80 MHz and to samples doped with neodymium and gadolinium. A detailed investigation has been made of the splitting of the ESR transitions in low concentration Gd (^3+) / CaWO (_4) reported first By Buckley in 1973; this has led to the proposition of an ordered oxygen vacancy model giving rise to two slightly different Gd environments in both of which Gd substitutes for Ca at calcium sites.
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